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Borotellurites

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Borotellurites are chemical mixed anion compounds that contain any kind of borate and tellurite ions bound together via oxygen. They are distinct from borotellurates in which tellurium is in +6 oxidation state. There are also analogous boroselenites, with selenium instead of tellurium, and borosulfates containing sulfur. Borotellurites are colourless.

List

chemmwcrystal systemspace groupunit cellvolumedensitycommentsreferences
K3BaTeB7O15monoclinicP21/ca=8.979 b=6.303 c=25.869 β=98.095°transparent above 235 nm [1]
LaTeBO5357.32orthorhombicPbcaa=10.8220 b=6.9216 c=11.5812 Z=8867.505.472colourless; large birefringence [2]

References

  1. Zhang, Ting; Deng, Li-Han; Xie, Wen-Long; Bai, Chun-Yan; Feng, Jun-Wei; Zheng, Jing-Jing; An, Dong-Hai (March 2022). "K3BaTeB7O15: A new borotellurite with mixed metal cations" . Journal of Molecular Structure. 1252 132181. doi:10.1016/j.molstruc.2021.132181.
  2. Wang, Jiankang; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2021). "LaTeBO5: a new borotellurite with a large birefringence activated by the highly distorted [Te(iv)O4] group" . Dalton Transactions. 50 (36): 12404–12407. doi:10.1039/D1DT01639C. ISSN   1477-9226. PMID   34184016.
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