Individuals with the given name Alessio
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- Alessio Ascalesi (1872–1952), Italian cardinal
- Alessio Bandieri (born 1974), Italian footballer
- Alessio Boni (born 1966), Italian actor
- Alessio Castro-Montes (born 1997), Belgian footballer
- Alessio Cerci (born 1987), Italian footballer
- Alessio Cragno (born 1994), Italian footballer
- Alessio Da Cruz (born 1997), Dutch footballer
- Alessio Deledda (born 1994), Italian racing driver
- Alessio Di Chirico (born 1989), Italian martial artist
- Alessio di Giovanni (1872–1946), Italian poet
- Alessio di Savino (born 1984), Italian boxer
- Alessio Donnarumma (born 1998), Italian footballer
- Alessio Figalli (born 1984), Italian mathematician (Fields medalist)
- Alessio Lapice (born 1991), actor
- Alessio Locatelli (born 1978), Italian footballer
- Alessio Lorandi (born 1998), Italian racing driver
- Alessio Mininni (born 1997), Italian singer-songwriter
- Alessio Morosin (born 1955), Italian lawyer
- Alessio Riccardi (born 2001), Italian footballer
- Miguel Alessio Robles, Mexican lawyer
- Alessio Romagnoli (born 1995), Italian footballer
- Alessio Sakara (born 1981), Italian martial artist
- Alessio Sestu (born 1983), Italian footballer
- Alessio Tacchinardi (born 1975), Italian footballer
